Part 3 – How To Make Soap Using SoapCalc (Advanced)

Find out how to modify your soap recipes: how to use a soap calculator – SoapCalc, how to add or remove an oil, change the color, use a different aroma, change the amount of water. If you plan to modify or personalize any soap recipe, this guide will guide you through the process. This is the 3rd part of the soap making learning series.

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Notes and Preparation

From my personal experience, the manufacture of soaps lives a lot to write down and prepare. Writing down the recipe and its results is very important to learn how to control how the ingredients interact.

Even when using the same amounts and ingredients, and because it is very difficult to reproduce all the steps (for example, replicating the exact temperatures at which the caustic soda solution and oils are when they are mixed), or because we simply changed supplier of a particular ingredient, it is usual not to be able to reproduce the same tone or aroma in soaps.

For this reason, annotation helps not to forget most of the variables. Writing down also helps NOT to repeat certain experiences again. This advice then becomes even more important when we want to personalize a soap recipe.

The preparation for the soap making operation itself has already been extensively described in the article Part 2 – How To Make Soap by Cold Process Step-by-Step. Weighing of ingredients, disposition, and availability of all utensils, the layout of the work areas, everything being prepared, and affixed is very important for the manufacture to run smoothly.

The preparation however also involves planning the recipe itself and purchasing the ingredients in advance. Especially if we want to do something new. The following chapters of this article will describe how to customize soap recipes to your liking.

However, it remains the advice, gained from experience, to always write down the recipes and the respective results, as well as to plan the recipe in advance before deciding to execute it.

Organização é fundamental para o fabrico de sabonetes correr bem

Reasons for Customizing a Recipe

Sometimes, running a soap recipe can be difficult because there are differences from region to region. For example, in Portugal it is difficult to find palm oil, in other regions of the planet it may be difficult to find olive oil – or it is very expensive. It may also be the case that those who make the soaps are allergic or sensitive to certain ingredients.

Here are some reasons for wanting to modify or personalize soap recipes:

  • Skin allergy or sensitivity
  • Cost and purchasing power
  • Local ingredient availability
  • Prefer vegetarian or vegan ingredients
  • Prefer all-natural ingredients
  • Avoid using palm oil (due to controversies in its cultivation and associated deforestation)
  • Prefer to use an ingredient you already have

Attention: Soap recipes are chemical formulas

For those who want to start making soap, a very important note: soap making is chemical. To make it clearer, soap recipes are not true “recipes”, but chemical formulas, even if we are talking about the manufacture of natural soaps.

Modifying or personalizing a soap recipe is not the same as giving a “touch” to a cake recipe. Hence the emphasis on using the right amounts with the right ingredients.

An experienced soap maker can create, change or customize soap recipes because he knows and understands which fats and what combination of fats creates a good bar of soap. This way, you can define the correct amount of caustic soda needed to turn the oils into soap.

If you are starting out, it would be preferable to try the basic soap recipes presented on this site, such as olive oil soap recipe, or coconut oil soap recipe. I am careful to use a small number of ingredients in them (and you can always choose not to use colorings or scents).

Oils: It is not as simple as changing one oil for another

Oil + Lye  = Soap

This formula, as well as its chemical principle, has already been described and explained in some articles of this blog.

However, it never hurts to repeat: oils and lye (caustic soda), when mixed, undergo a chemical process called saponification. It is through this process that the lye and oils bond and form soap. In a cake, the flour and eggs and all the other ingredients used in making them are still there in some way.

In a soap recipe that uses olive oil, it will be transformed from oil to Sodium Olivate, ceasing to be olive oil and becoming a new compound, part of the olive soap. Other types of oils undergo the same transformation: coconut oil becomes Sodium Cocoate, sunflower oil becomes Sodium Sunflowerate, and so on. These are English terms that follow the INCI standard.

In soap recipes, each oil is chosen for a specific purpose, and the amount of caustic soda (NaOH or KOH) is calculated to be the exact amount to saponify it. In most cases, “superfat” is also used, which means that there is a percentage of oils that will not be saponified, being used in soaps as moisturizing and conditioning agents.

That is, this whole process is compromised when we change the oils or their quantities without any type of adjustment. That is why it is not possible to simply add a “pinch” here, remove “a little” there or even change this oil for that one, because lye is precisely calculated for the oils in the recipe and their quantities and not for other.

By modifying the oil mix without adjusting the amount of water and lye, you can end up with a batch of rotten soaps. Or worse, one that causes irritation or even minor skin burns !!!

Learn from tried and tested recipes, invent later!

The basic soap recipes presented on this site are simple, use relatively few ingredients, and are usually in small quantities, exactly to guide beginners in the soap making process without major disasters 🙂 Many of the ingredients are found in supermarkets and there are specialty stores, such as Plena Natura, of Portuguese origin, which sells ingredients for soaps, among others, at affordable prices.

I sincerely recommend you to try these recipes already tested and follow from beginning to end the posts about Part 1 – How To Make Soap From Scratch and Part 2 – How To Make Soap by Cold Process Step-by-Step and presented on this website, before starting to venture into new recipes.

I must confess that I also wanted to try personalized recipes for myself at first, and “invented” my first recipe. The soap, although it was not a complete ruin, turned into “chalk” over time, as it had too much lye. Exactly because I replaced one oil with another without recalculating anything.

From there, I followed this website, the Lovely Greens, which I loved for embracing everything that is natural, but without fundamentalisms, in a practical, reasonable and unpretentious tone. They can and should use it as a reference too, if they speak English well. It is my reference and inspiration for HerbAlcochete.

I never had problems with soap again !! They might not have the expected color or aroma, but they were always very good, so I never used products purchased for the bath again.

Using soap calculators: SoapCalc

From this point on, it is assumed that the reader has knowledge of the previous posts about cold process soap making. If you haven’t read any yet, I suggest reading the following posts by order:

Whenever you need to modify or customize a soap recipe, the first step is to use a soap calculator like SoapCalc. The idea is to recreate the original recipe in SoapCalc and edit it from there.

You should start by selecting options 1 and 2 which are, correspondingly, the type of soda (NaOH) and the units of measurement (grams). Make sure that the soda and measuring units match those in the recipe.

Skip options 3 to 5 and add the ingredients in option 6. the list of ingredients is on the side.

Here are some translations:

Make sure, after adding the ingredients, that the weight option is chosen and not the%. Record for each ingredient the weight indicated in the recipe (in grams). Then, press the button in option 7 “1.Calculate Recipe”, followed by button “2. View or Print Recipe ”. A new tab will open in the browser, with the quantities of oils inserted, and the amount of water and lye calculated for the recipe.
There should be discrepancies in the values ​​of water and soda.

Customize recipes with SoapCalc

Adjust the “Superfat”

There are quite a few recipes that indicate the percentage of “Superfat” that exists in the recipe (“Superfat” is the percentage of oils in the recipe that do not saponify. See more at Part 2 – How To Make Soap by Cold Process Step-byStep ).

In this case, enter the amount of revenue in option 4 “Superfat”.

However, many recipes do not have this value explicitly indicated so the amount of lye in SoapCalc, compared to the recipe, may be different.

The “Superfat” of handmade soaps is typically between 3% – 8% (with the exception of coconut oil soap). Laundry soap has a “Superfat” of 0%. Some bars of soap for washing hair contain “Superfat” of 15%.

Modify the value in option 4 “Superfat”, starting at 5% and clicking on the buttons in option 7, until you obtain a recipe with the same amount of caustic soda as the original recipe.

Do not worry about the water values ​​and option 3 – everything will be explained in the following section “Amount of water in the recipe”.

Modify recipe oils

Once you have all the original recipe values ​​entered in SoapCalc, it’s time to start customizing the recipe.

Take note of the values ​​related to Soap Qualities in option 5 (Soap Qualities): hardness (Hardness), cleanliness (Cleansing), hydration (Condition), foam (Bubbly), creaminess (Creamy). Also note the total weight of oils (option 2), water values ​​(option 3) and “Superfat” (option 4). The changes you make to the recipe should keep all of these values ​​close to those of the original recipe.

Now remove / add the ingredients to be modified, making sure that the total weight of oils (option 2) always remains the same.

It may take some time to adjust the quantities and types of the various oils until you get a similar recipe. Most of the time, you will need a combination of oils to replace one. An exception is palm oil and animal fat (lard). Both are fats that saponify very similarly and have a profile of fat acids similar.

TIP: As a rule of thumb, use a 40:60 percentage of saturated oils (solid fats) / unsaturated oils (liquid fats). It doesn’t have to be strict, but it is good practice when formulating new recipes. See the values ​​at the end of option 5 (Sat: Unsat).

Amount of water in the recipe

It is normal for most soap recipes to have smaller amounts of water than those indicated by SoapCalc – see option 3.

Water has 2 essential roles in a soap recipe.

  1. Dissolve the caustic soda in an aqueous solution that can be mixed homogeneously with the oils and start saponification
  2. Increase or decrease the speed at which the trace is reached. The less water you use, the faster you reach trace. The more you use it, the longer it will take to reach trace.

For example, 100% olive oil soap takes less water, as this oil delays the trace a lot. If we use a high amount of water, it can take about 30 minutes to beat the dough until it reaches trace.

By default, SoapCalc gives a water content of 38% of oils (Water as% of oils: 38%).

However, sizing the amount of water by percentage of oils can be misleading. This is because for any two different recipes that take 450g of oils, the percentage of lye will be different – different oils require different amounts of lye to saponify.

Let’s assume that one of these recipes requires 60g of soda and the other, 80g of soda. Measuring the amount of water by percentage of oils, both recipes require 171g of water. That is, 38% of 450g.

However, the first recipe will have a weaker aqueous solution of caustic soda (60g soda + 171g water) and will reach trace slowly, while the second (80g soda + 171g water) has a stronger caustic solution and will arrive to trace much faster.

Create/Modify lye water

The best way to calculate the amount of water, will be starting with the amount of lye that the recipe uses.

When creating lye water for soaps, the standard percentage of lye is 25-28%. This value is the same as option 3 “Lye Concentration”. Basically, for a 25% aqueous soda solution we have 1 part of soda and 3 parts of water. That is, for a quantity of soda of 60g, the amount of water will be 3 times that of soda ie 180g (3 x 60g).

In soap making, it is normal to use a concept called “Water discount”. This simply means using a stronger soda concentration, above the standard, which, as already mentioned, allows you to get to the mix more quickly. Other desirable effects are that it reduces the curing time and prevents the problem of “soda ash” (the soap becomes whitish on its surface).

For simple recipes that use only a dye based on olive oil or coconut oil, I usually use a lye concentration of 33% -36%. The count is easy: 36% = 36/100 = 0,36; the inverse of 0,36 is 1 / 0,36 = 2,77; 2.77 – 1 = 1.77.

That is, for a lye concentration of 36%, we are left with 1 part of lye and 1.77 parts of water: now just multiply the amount of lye by 1.77 to obtain the amount of water. For example, 58g of lye and 103g of water.

The strongest lye concentration you can use is 50% (1 part lye and 1 part water, that is, the amount of lye and water are equal).

It is not recommended to use a solution so strong in soaps, since the soap dough can reach trace so fast that it will solidify in the bowl. On the other hand, soda can have difficulties in dissolving in water, especially if the ambient temperature is above 25ºC. This can result in solid pieces of lye stuck inside the soap waiting to cause skin burns …

Soap Making Oils

In option 5 of the SoapCalc a list of terms that look like chemical expressions are listed. This option shows the fatty acid profile of the soap recipe. Each of these expressions, lauric acid, myristic acid, etc. represents the individual amount of each of these fatty acids in the oils used in the recipe.

Fatty acids are the constituents of an oil and each provides unique properties to the soap. These properties can be silky foam, stable foam, more or less soap bubbles, hydration, hardness and durability of the soap, among others.

The following table shows, for each fatty acid, the type of properties it supplies to the soap, as well as the oils where it is present in greater quantities. Oils are listed from a higher percentage of that fatty acid to a lower percentage. The oils that are most easily found in Portugal are highlighted:

Fatty AcidProperties it provides to soapOils where it is present
Lauric AcidHardnesspalm seed oil, coconut oil, babassu oil
Miristic AcidHardness, Cleanliness, Soft Foamcoconut oil, palm seed oil, Babassu oil
Palmitic AcidHardness, Creamy Texture, Stable Foamstearic acid / stearin, palm oil (RSPO), soy wax, cocoa butter, animal fat (lard)
Stearic acidHardness, Creamy Texture, Stable Foamstearic acid / stearin, butter of Shorea Robusta (Salt), butter of Shorea Stenoptera (Illipe), shea butter, mango butter, cocoa butter
Oleic acidHydration, Sliding Texturesunflower oil, japanese camellia Oil, olive oil, hazelnut oil, shea oil, sweet almond oil, apricot kernel oil, peach kernel oil, canola oil, avocado oil, peanut oil, shea butter
Linoleic acidHydration, Silky Textureevening primrose oil, grapeseed oil, poppy seed oil, passion fruit oil, hemp oil, cotton oil, corn oil, rapeseed oil, hemp seed oil, soy oil
Linolenic AcidHydration, Softnesshemp oil, linseed oil, and in lower percentages in olive oil and sunflower oil
Ricinoleic AcidHydration, Stable Foamcastor oil

When creating or customizing a soap recipe, so that we don’t get caught up in the middle of so much variable, it is important to pay attention to Soap Qualities in option 5, especially the value of the INS parameter: you must always try to approximate the recipe to the recommended value ranges.

Many soapmakers may claim that they have created great recipes with some values ​​outside these recommended ranges. However, they become a good standard to follow and I have not yet experienced a bad recipe every time I follow these guidelines.

The following list shows the most common oils used in soap making and the recommended percentages in recipes:

Customize the soap fragrance

When we want to personalize a soap recipe, we often just want to use a different scent. When it comes to using essential oils or fragrances, it is necessary to be equally rigorous in using the right amount. If it is too little, the soap scent may be too weak. If used too much it can cause complications such as skin irritations or allergies.

There is a difference between essential oils and fragrances. Fragrances are not completely natural, they are basically patented perfumes. Some fragrances can only be used on candles, others are safe for the skin. They usually come with recommendations on how much to use in “leave-in” products (lotions, creams, etc.) and in wash-off products (soaps, shampoos, etc.). Always follow these recommendations. If the quantities to be used are not clear for a particular fragrance, contact the manufacturer.

SoapCalc has its own field to be able to know what the maximum fragrance value can be used in the manufacture of soap, see the “fragrance” field in option 4, be it essential oils or fragrances. The value is in g / kg soap, that is, 31g / kg fragrance corresponds to 15,5g for 500g of soap and 31g for 1 kg of soap. However, this indication should never override the manufacturer’s recommendations.

Modify a fragrance

It can be confusing to understand how to apply fragrance recommendations.

Basically, in the particular case of soaps, if the maximum percentage of use for a fragrance is 3%, it will be 3% of the total weight of oils, caustic soda and the fragrance itself. The water does not count for the total weight of the soap, as it will disappear completely during curing.

Therefore, for 450g of soap, the amount of fragrance is 13,5g (450g x 0,03 = 13,5g).

Modify essential oils

Essential oils are distinguished from fragrances because they are more natural. Essencial oils are volatile aromatic compounds extracted from aromatic plants by distillation or fruit compression processes. They are not formulated in the laboratory, they are limited to a high concentration of essential oils from the plants themselves.

Thus, while fragrances work well using only one, as they are a specifically formulated perfume, essential oils are different: they work best in mixtures, although there are some that can be used alone.

Mixtures of essential oils consist of one or more oils, but mixtures that work best are those that contain at least one base note essential oil, one middle note essential oil, and one top note essential oil (which is smelled first). See also Essential Oils to Make Soap.

For beginners, the advice is to start by using one or two essential oils to taste and start with mixtures with more experience. Very common essential oils are: lavender, eucalyptus, rosemary, sweet orange, peppermint, lemongrass and rose (rose absolute, normally diluted) .

Regarding the quantity to be used, the maximum value of 31g / kg is a good reference, however, soon one realizes that essential oils are expensive and 31g weighs a little in the wallet, especially for an optional ingredient. Although it is not a correct approximation, because the densities of the different essential oils are different, I usually approach the SoapCalc value of 31g in ml, and use 31 ml of essential oils in 1Kg recipes, or 13ml in 450g recipes which are common on this website.

Customizing soap color

There may be a soap recipe that you are interested in trying, but you want to change the color, or the type of dye. In this case, the change is simpler, as it is enough to replace the original dye with another one. You can also not use any type of dye and leave the soap with its natural color, derived from the oils used.

There are numerous ingredients that can be used as dyes for soaps. Some are natural, others are not. Some are reliable and easy to use, others are a little more unpredictable. I confess that, despite never having bad results, the issue of dye is the one that gets out of my control. It is very common to try to obtain a certain color and turn out the color on the side: instead of orange, I obtained yellow or mustard color.

Attention to the color that is obtained when the soap is removed from the molds, 24 to 48 hours after manufacture, it usually differs slightly from the final color. There is no point in throwing out any soap production because we wanted lilac and it came out grayish brown. The color of the soap changes with healing. Always wait 4 to 6 weeks to see the result. In addition, you can always use the soap even with an ugly color 🙂

In the recipes I make, I always try to use kitchen ingredients and plants to add color to the soaps, however, until now I have only succeeded in controlling the tones by using the most common natural mineral dyes: oversea, iron and chromium oxides, micas and even cosmetic clays.

The topic of dyes will be dealt with in more detail in another article.

Hope you found this article helpful! If you still have any questions or wish to make a suggestion, please, leave a comment below.

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